Accessory minerals are minerals found in igneous rocks that are not used for the classification or naming of the rock. These minerals may be commonly present in a type of rock, but the absence of the mineral would not change the general classification geologists give to the rock.
The two accessory minerals in the center of the picture above are greenish-black needles of aegirine (AY-jur-EEN) and orangish-pink analcime (uh-NAL-seem) crystals. These minerals are frequently found together in igneous intrusions of syenite like the one present at Granite Mountain, where this sample was collected.
Accessory minerals give important clues to geologists when trying to determine details about how a rock formed and how it changed over time. They can make up a substantial portion or a fairly insignificant portion of a rock. Some accessory minerals make up a sufficient portion of the rock to be included as a modifier in the name, such as “biotite syenite”. Adding such a modifier gives geologists quick and useful information about how this rock differs from standard syenite.
(FOV approx. 1.5 mm, photo courtesy of Stephen Stuart)
The metallic crystal in the center of the photo above is a mineral known as brookite. It was collected in Magnet Cove, AR. This particular crystal is approximately 0.5 mm in diameter.
Brookite is one of three forms of titanium oxide (TiO2) that naturally occur in Arkansas. These three forms are what are known as “polymorphs”. Polymorphs are minerals that have the same chemical composition but their atoms are arranged differently creating differing crystal structures. It’s the mineral equivalent of being a fraternal twin instead of an identical twin!
The three types of TiO2 crystal found in Arkansas are brookite, anatase, and rutile. When geologists talk about a mineral’s stability, they are talking about how much of a change in temperature and/or pressure (stress) is necessary to change the crystal structure or composition. The more stress required to change it, the more stable the mineral. Brookite is the least stable of the three forms and therefore the rarest. Typically, brookite crystals are yellowish or reddish brown in color, but the variety found in Arkansas is commonly black which is due to the presence of the element niobium (Nb) as an impurity.
This mineral usually occurs around metamorphic rocks or igneous intrusions similar to the intrusion at Magnet Cove.